Identification of an intermediate in the deboronation of ortho-carborane: an adduct of ortho-carborane with two nucleophiles on one boron atom.
نویسندگان
چکیده
The 1 : 2 adduct of 1-bromo-ortho-carborane and pyridine has been identified as a significant intermediate in the deboronation of ortho-carborane to a nido-anion.
منابع مشابه
Deactivation of the coordinating ability of the iminophosphorane group by the effect of ortho-carborane.
The C-carboranyl iminophosphorane compounds derived from triphenylphosphine (I1) and o-(methylthiophenyl)-diphenylphosphine (I2) were obtained and structurally characterized. Functionalization with sulfur on the other cage carbon atom gave the corresponding disulfides (L1L1 and L2L2). In the case of I1 it was also possible to isolate the trisulfide (L1SL1) and the thiol (L1H), which is not in t...
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ورودعنوان ژورنال:
- Chemical communications
دوره 17 شماره
صفحات -
تاریخ انتشار 2008